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1 article(s) from Haav, Kristjan

Design, synthesis and application of carbazole macrocycles in anion sensors

Alo Rüütel,
Ville Yrjänä,
Sandip A. Kadam,
Indrek Saar,
Mihkel Ilisson,
Astrid Darnell,
Kristjan Haav,
Tõiv Haljasorg,
Lauri Toom,
Johan Bobacka and
Ivo Leito

Beilstein J. Org. Chem. 2020, 16, 1901–1914, doi:10.3762/bjoc.16.157

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Graphical Abstract

Figure 1: The biscarbazolylurea moiety.

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Figure 2: The structure of the solid-contact ion-selective electrode (sensor): a) glassy carbon as the electr...

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Figure 3: Studied receptor molecules.

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Figure 4: MC001 and MC003 lowest energy conformers (COSMO-RS) showing intramolecular bonds. Color coding: whi...

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Figure 5: a) Complex of MC008 with acetate; b) complex of MC006 with formate; c) complex of MC007 with lactat...

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Scheme 1: The synthetic pathway to receptors CZ016 and MC001–MC014. The reaction yield for 2–3a/3b is given a...

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Figure 6: Binding affinities of the studied receptors towards different carboxylates in DMSO-d₆/H₂O (99.5%:0....

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Figure 7: Impedance spectra of sensors with each of the membranes. The spectra were recorded in 0.1 M sodium ...

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Figure 8: Calibration curves for each of the membranes. The calibrations were performed by diluting 0.1 M sod...

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Figure 9: The influence of solution pH on the potential responses of the sensor prototypes (three sensors for...

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Figure 10: Potentiometric selectivity coefficients of interfering anions (relative to acetate) determined usin...

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Published 04 Aug 2020

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